From Developer, click on the administration tab. Under Configuration Managers select Subscriptions. The Error " The key is already associated with an element of this collection" appears.

This is a known Defect. Some duplicated children instances of a subscription exists in the Metadata. While Web and Command Manager are not affected by the duplicate, Developer cannot handle the duplicated instance well.
Workarounds to view the subscriptions:
ACTION:
Changes made into Strategy build 11.1 to prevent this error. Please upgrade to take this version to advantage of a fix.